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Methane

|Section2={{Chembox Properties | C=1 | H=4 | Appearance = Colorless gas | Odor = Odorless | Density = {{ubl | 0.656g/L (gas, 25°C, 1atm) | 0.716g/L (gas, 0°C, 1atm) | 0.42262g/cm3 (liquid, −162°C) }} | MeltingPtK = 90.7 | BoilingPtK = 111.66 | Solubility = 22.7 mg/L | SolubleOther = Soluble in ethanol, diethyl ether, benzene, toluene, methanol, acetone | LogP = 1.09 | HenryConstant = 14 nmol·Pa−1·kg−1 | MagSus = −12.2 cm3/mol }} |Section3={{Chembox Structure | MolShape = Tetrahedron | Dipole = 0 D | PointGroup = Td }} |Section4={{Chembox Thermochemistry | DeltaHf = −74.87 kJ/mol | DeltaHc = −891.1 to −890.3 kJ/mol | Entropy = 186.25 J/(K·mol) | HeatCapacity = 35.69 J/(K·mol) }} |Section5={{Chembox Hazards | Hazards_ref = | GHSPictograms = | GHSSignalWord = DANGER | HPhrases = | PPhrases = | NFPA-H = 2 | NFPA-F = 4 | NFPA-R = 0 | NFPA-S = SA | FlashPtC = −188 | AutoignitionPtC = 537 | ExploLimits = 4.4–17% }} |Section6={{Chembox Related | OtherFunction_label = alkanes | OtherFunction = }} }} Methane ( or ) is a chemical compound with the chemical formula (one atom of carbon and four atoms of hydrogen). It is a group-14 hydride and the simplest alkane, and is the main constituent of natural gas. The relative abundance of methane on Earth makes it an attractive fuel, though capturing and storing it poses challenges due to its gaseous state under normal conditions for temperature and pressure. Natural methane is found both below ground and under the sea floor. When it reaches the surface and the atmosphere, it is known as atmospheric methane. The Earth's atmospheric methane concentration has increased by about 150% since 1750, and it accounts for 20% of the total radiative forcing from all of the long-lived and globally mixed greenhouse gases.

History

In November 1776, methane was first scientifically identified by Italian physicist Alessandro Volta in the marshes of Lake Maggiore straddling Italy and Switzerland. Volta was inspired to search for the substance after reading a paper written by Benjamin Franklin about "flammable air".Volta, Alessandro (1777) Lettere del Signor Don Alessandro Volta ... Sull' Aria Inflammabile Nativa delle Paludi of Signor Don Alessandro Volta ... on the flammable native air of the marshes, Milan, Italy: Giuseppe Marelli. Volta collected the gas rising from the marsh, and by 1778 had isolated the pure gas. He also demonstrated that the gas could be ignited with an electric spark. The name "methane" was coined in 1866 by the German chemist August Wilhelm von Hofmann.See:

Properties and bonding

Methane is a tetrahedral molecule with four equivalent C–H bonds. Its electronic structure is described by four bonding molecular orbitals (MOs) resulting from the overlap of the valence orbitals on C and H. The lowest energy MO is the result of the overlap of the 2s orbital on carbon with the in-phase combination of the 1s orbitals on the four hydrogen atoms. Above this energy level is a triply degenerate set of MOs that involve overlap of the 2p orbitals on carbon with various linear combinations of the 1s orbitals on hydrogen. The resulting "three-over-one" bonding scheme is consistent with photoelectron spectroscopic measurements. At room temperature and standard pressure, methane is a colorless, odorless gas. The familiar smell of natural gas as used in homes is achieved by the addition of an odorant, usually blends containing tert-butylthiol, as a safety measure. Methane has a boiling point of −161 ° C (−257.8 ° F) at a pressure of one atmosphere. Methane Phase change data. NIST Chemistry Webbook. As a gas it is flammable over a range of concentrations (5.4–17%) in air at standard pressure. Solid methane exists in several modifications. Presently nine are known. Cooling methane at normal pressure results in the formation of methane I. This substance crystallizes in the cubic system ( space group Fm3m). The positions of the hydrogen atoms are not fixed in methane I, i.e. methane molecules may rotate freely. Therefore, it is a plastic crystal.

Chemical reactions

The primary chemical reactions of methane are combustion, steam reforming to syngas, and halogenation. In general, methane reactions are difficult to control. Partial oxidation to methanol, for example, is challenging because the reaction typically progresses all the way to carbon dioxide and water even with an insufficient supply of oxygen. The enzyme methane monooxygenase produces methanol from methane, but cannot be used for industrial-scale reactions.

Acid-base reactions

Like other hydrocarbons, methane is a very weak acid. Its pKa in DMSO is estimated to be 56. It cannot be deprotonated in solution, but the conjugate base with methyllithium is known. A variety of positive ions derived from methane have been observed, mostly as unstable species in low-pressure gas mixtures. These include methenium or methyl cation , methane cation , and methanium or protonated methane . Some of these have been detected in outer space. Methanium can also be produced as diluted solutions from methane with superacids. Cations with higher charge, such as and , have been studied theoretically and conjectured to be stable. Despite the strength of its C–H bonds, there is intense interest in catalysts that facilitate C–H bond activation in methane (and other lower numbered alkanes).

Combustion

Methane's heat of combustion is 55.5 MJ/kg. Energy Content of some Combustibles (in MJ/kg). People.hofstra.edu. Retrieved on March 30, 2014. Combustion of methane is a multiple step reaction. The following equations are part of the process, with the net result being CH4 + 2 O2 → CO2 + 2 H2O (ΔH = −891 k J/ mol, at standard conditions)
  1. CH4+ M* → CH3 + H + M
  2. CH4 + O2 → CH3 + HO2
  3. CH4 + HO2 → CH3 + 2 OH
  4. CH4 + OH → CH3 + H2O
  5. O2 + H → O + OH
  6. CH4 + O → CH3 + OH
  7. CH3 + O2 → CH2O + OH
  8. CH2O + O → CHO + OH
  9. CH2O + OH → CHO + H2O
  10. CH2O + H → CHO + H2
  11. CHO + O → CO + OH
  12. CHO + OH → CO + H2O
  13. CHO + H → CO + H2
  14. H2 + O → H + OH
  15. H2 + OH → H + H2O
  16. CO + OH → CO2 + H
  17. H + OH + M → H2O + M*
  18. H + H + M → H2 + M*
  19. H + O2 + M → HO2 + M*
The species M* signifies an energetic third body, from which energy is transferred during a molecular collision. Formaldehyde (HCHO, or ) is an early intermediate (reaction 7). Oxidation of formaldehyde gives the formyl radical (HCO; reactions 8–10), which then give carbon monoxide (CO) (reactions 11, 12 & 13). Any resulting H2 oxidizes to H2O or other intermediates (reaction 14, 15). Finally, the CO oxidizes, forming CO2 (reaction 16). In the final stages (reactions 17–19), energy is transferred back to other third bodies. The overall reaction rate is a function of the concentration of the various entities during the combustion process. The higher the temperature, the greater the concentration of radical species, and the more rapid the combustion process.

Reactions with halogens

Given appropriate conditions, methane reacts with halogens as follows: X2 + UV → 2 X• X• + CH4 → HX + CH3• CH3• + X2 → CH3X + X• where X is a halogen: fluorine (F), chlorine (Cl), bromine (Br), or iodine (I). This mechanism for this process is called free radical halogenation. It is initiated with UV light or some other radical initiator. A chlorine atom is generated from elemental chlorine, which abstracts a hydrogen atom from methane, resulting in the formation of hydrogen chloride. The resulting methyl radical, CH3•, can combine with another chlorine molecule to give methyl chloride (CH3Cl) and a chlorine atom. This chlorine atom can then react with another methane (or methyl chloride) molecule, repeating the chlorination cycle. Similar reactions can produce dichloromethane (CH2Cl2), chloroform (CHCl3), and, ultimately, carbon tetrachloride (CCl4), depending upon reaction conditions and the chlorine to methane ratio.

Uses

Methane is used in industrial chemical processes and may be transported as a refrigerated liquid (liquefied natural gas, or LNG). While leaks from a refrigerated liquid container are initially heavier than air due to the increased density of the cold gas, the gas at ambient temperature is lighter than air. Gas pipelines distribute large amounts of natural gas, of which methane is the principal component.

Fuel

Methane is used as a fuel for ovens, homes, water heaters, kilns, automobiles, turbines, and other things. It combusts with oxygen to create heat, as demonstrated by a British inventor in a 1974 film of the National Film Board of Canada.https://www.nfb.ca/film/bates_car_sweet_as_a_nut/

Natural gas

Methane is important for electricity generation by burning it as a fuel in a gas turbine or steam generator. Compared to other hydrocarbon fuels, methane produces less carbon dioxide for each unit of heat released. At about 891 kJ/mol, methane's heat of combustion is lower than any other hydrocarbon but the ratio of the heat of combustion (891 kJ/mol) to the molecular mass (16.0 g/mol, of which 12.0 g/mol is carbon) shows that methane, being the simplest hydrocarbon, produces more heat per mass unit (55.7 kJ/g) than other complex hydrocarbons. In many cities, methane is piped into homes for domestic heating and cooking. In this context it is usually known as natural gas, which is considered to have an energy content of 39 megajoules per cubic meter, or 1,000 BTU per standard cubic foot. Methane in the form of compressed natural gas is used as a vehicle fuel and is claimed to be more environmentally friendly than other fossil fuels such as gasoline/ petrol and diesel. Research into adsorption methods of methane storage for use as an automotive fuel has been conducted.

Liquefied natural gas

Liquefied natural gas (LNG) is natural gas (predominantly methane, CH4) that has been converted to liquid form for ease of storage or transport. Liquefied natural gas takes up about 1/600th the volume of natural gas in the gaseous state. It is odorless, colorless, non-toxic and non-corrosive. Hazards include flammability after vaporization into a gaseous state, freezing, and asphyxia. The liquefaction process involves removal of certain components, such as dust, acid gases, helium, water, and heavy hydrocarbons, which could cause difficulty downstream. The natural gas is then condensed into a liquid at close to atmospheric pressure (maximum transport pressure set at around ) by cooling it to approximately . LNG achieves a higher reduction in volume than compressed natural gas (CNG) so that the energy density of LNG is 2.4 times greater than that of CNG or 60% that of diesel fuel. This makes LNG cost efficient to transport over long distances where pipelines do not exist. Specially designed cryogenic sea vessels ( LNG carriers) or cryogenic road tankers are used for its transport. LNG, when it is not highly refined for special uses, is principally used for transporting natural gas to markets, where it is regasified and distributed as pipeline natural gas. It is also beginning to be used in LNG-fueled road vehicles. For example, trucks in commercial operation have been achieving payback periods of approximately four years on the higher initial investment required in LNG equipment on the trucks and LNG infrastructure to support fueling. However, it remains more common to design vehicles to use compressed natural gas. , the relatively higher cost of LNG production and the need to store LNG in more expensive cryogenic tanks had slowed widespread commercial use.Fuels of the Future for Cars and Trucks, Dr. James J. Eberhardt, U.S. Department of Energy, 2002 Diesel Engine Emissions Reduction (DEER) Workshop, August 25–29, 2002

Liquid methane rocket fuel

In a highly refined form, liquid methane is used as a rocket fuel. Though methane has been investigated for decades, no production methane engines have yet been used on orbital spaceflights. Methane is reported to offer the advantage over Kerosene of depositing less carbon on the internal parts of rocket motors, reducing the difficulty of re-use of boosters. Since the 1990s, a number of Russian rockets using liquid methane have been proposed. One 1990s Russian engine proposal was the RD-192, a methane/ LOX variant of the RD-191. In 2005, US companies, ORBITEC (Orbital Technologies Corporation, now part of Sierra Nevada Corporation as of 2014) and XCOR Aerospace, developed a demonstration liquid oxygen/liquid methane rocket engine and a larger -thrust engine in 2007 for potential use as the CEV lunar return engine, before the CEV program was later cancelled. More recently the American private space company SpaceX announced in 2012 an initiative to develop liquid methane rocket engines, including initially, the very large Raptor rocket engine. Raptor is being designed to produce of thrust with a vacuum specific impulse (Isp) of 363 seconds and a sea-level Isp of 321 seconds, and began component-level testing in 2014. In February 2014, the Raptor engine design was shown to be of the highly efficient and theoretically more reliable full-flow staged combustion cycle type, where both propellant streams—oxidizer and fuel—are completely in the gas phase before they enter the combustion chamber. Prior to 2014, only two full-flow rocket engines had ever progressed sufficiently to be tested on test stands, but neither engine completed development or flew on a flight vehicle. In 2016, a development Raptor engine was tested.{{cite news | title = Elon Musk reveals first photos of SpaceX’s powerful new Raptor engine | newspaper =ars technica | date = 26 September 2016 | url = https://arstechnica.com/science/2016/09/elon-musk-reveals-first-photos-of-spacexs-powerful-new-raptor-engine/ | accessdate = 7 November 2016 }} In October 2013, the China Aerospace Science and Technology Corporation, a state-owned contractor for the Chinese space program, announced that it had completed a first ignition test on a new LOX methane rocket engine. No engine size was provided. In September 2014, another American private space company— Blue Origin— publicly announced that they were into their third year of development work on a large methane rocket engine. The new engine, the Blue Engine 4, or BE-4, has been designed to produce of thrust. While initially planned to be used exclusively on a Blue Origin proprietary launch vehicle, it will now be used on a new United Launch Alliance (ULA) engine on a new launch vehicle that is a successor to the Atlas V. ULA indicated in 2014 that they will make the maiden flight of the new launch vehicle no earlier than 2019. One advantage of methane is that it is abundant in many parts of the solar system and it could potentially be harvested on the surface of another solar-system body (in particular, using methane production from local materials found on Mars or Titan), providing fuel for a return journey. By 2013, NASA's Project Morpheus had developed a small restartable LOX methane rocket engine with thrust and a specific impulse of 321 seconds suitable for inspace applications including landers. Small LOX methane thrusters were also developed suitable for use in a Reaction Control System (RCS). SpaceNews is reporting in early 2015 that the French space agency CNES is working with Germany and a few other governments and will propose a LOX/methane engine on a reusable launch vehicle by mid-2015, with flight testing unlikely before approximately 2026.

Chemical feedstock

Although there is great interest in converting methane into useful or more easily liquefied compounds, the only practical processes are relatively unselective. In the chemical industry, methane is converted to synthesis gas, a mixture of carbon monoxide and hydrogen, by steam reforming. This endergonic process (requiring energy) utilizes nickel catalysts and requires high temperatures, around 700–1100 °C: CH4 + H2O → CO + 3 H2 Related chemistries are exploited in the Haber-Bosch Synthesis of ammonia from air, which is reduced with natural gas to a mixture of carbon dioxide, water, and ammonia. Methane is also subjected to free-radical chlorination in the production of chloromethanes, although methanol is a more typical precursor.Rossberg, M. et al. (2006) "Chlorinated Hydrocarbons" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim. Other commercially viable processes that use methane as a chemical feedstock include, the catalytic oxidation of methane into methanol based on the oxidative coupling of methane, and the direct reaction of methane with sulfur trioxide to produce methanesulfonic acid. June 27, 2016 Issue – Vol. 94 Issue 26 Chemical & Engineering News|last=McCoy|first=Michael|website=cen.acs.org|access-date=2016-11-07}}

Generation

, Sabatier reaction|300px|thumb| ]]

Geological routes

There are two main routes for geological methane generation, organic (thermogenic), and inorganic ( abiotic, meaning non-living). Thermally generated methane, is referred to as thermogenic, originating from deeper sedimentary strata. Thermogenic methane (CH4) formation occurs due to the break-up of organic matter, forced by elevated temperatures and pressures. This type of methane is considered to be the primary methane type in sedimentary basins, and from an economical perspective the most important source of natural gas. Thermogenic methane components are generally considered to be relic (from an earlier time). Generally, formation of thermogenic methane (at depth), can occur through organic matter break-up, or organic synthesis, both ways can involve microorganisms (methanogenesis) but may also occur inorganically. The involved anaerobic and aerobic processes can also consume methane, with and without microorganisms.The more important source of methane at depth (crystalline bedrock) is abiotic. Abiotic means that the methane formation took place involving inorganic compounds, without biological activity, magmatic or created at low temperatures and pressures through water-rock reactions.

Biological routes

Naturally occurring methane is mainly produced by microbial methanogenesis. This multistep process is used by microorganisms as an energy source. The net reaction is CO2 + 8 H+ + 8 e− → CH4 + 2 H2O The final step in the process is catalyzed by the enzyme Coenzyme-B sulfoethylthiotransferase. Methanogenesis is a form of anaerobic respiration used by organisms that occupy landfill, ruminants (e.g., cattle), and the guts of termites. It is uncertain whether plants are a source of methane emissions.Thomas, Claire (January 14, 2009) "Methane Emissions? Don't Blame Plants", Science Magazine.

Industrial routes

There are many technological methane production methods. Methane created from biomass in industrial plants via biological route is called biogas. A more synthetic method to produce methane is hydrogenating carbon dioxide through the Sabatier process. Methane is also a side product of the hydrogenation of carbon monoxide in the Fischer–Tropsch process, which is practiced on a large scale to produce longer-chain molecules than methane. Example of large-scale coal-to-methane gasification is the Great Plains Synfuels plant, started in 1984 in Beulah, North Dakota as a way to develop abundant local resources of low-grade lignite, a resource that is otherwise very hard to transport for its weight, ash content, low calorific value and propensity to spontaneous combustion during storage and transport. Methane as natural gas has been so abundant that synthetic production of it has been limited to special cases and as of 2016 covers only minor fraction of the methane used.

Power to methane

Power to methane is a technology that uses electrical power to produce hydrogen from water by electrolysis and uses the Sabatier reaction to combine hydrogen with carbon dioxide to produce methane. As of 2016, this is mostly under development and not in large-scale use. Theoretically, the process could be used as a buffer for excess and off-peak power generated by highly fluctuating wind generators and solar arrays. The conversion efficiency of power to methane is 49–65%, and full power–methane–power cycle is 30–38%.

Laboratory synthesis

Methane can be produced by the destructive distillation of acetic acid in the presence of soda lime or similar. Acetic acid is decarboxylated in this process. Methane can be prepared from aluminium carbide by reaction with water or strong acids. It is also made by reducing a solution of methanol and concentrated hydrochloric acid with iron powder, giving water and ferrous chloride as byproducts.

On Mars

Methane has been proposed as a possible rocket propellant on future Mars missions due in part to the possibility of synthesizing it on the planet by in situ resource utilization. An adaptation of the Sabatier methanation reaction may be used with a mixed catalyst bed and a reverse water-gas shift in a single reactor to produce methane from the raw materials available on Mars, utilizing water from the Martian subsoil and carbon dioxide in the Martian atmosphere. Methane could also be produced by a non-biological process called serpentinization involving water, carbon dioxide, and the mineral olivine, which is known to be common on Mars.

Occurrence

Methane was discovered and isolated by Alessandro Volta between 1776 and 1778 when studying marsh gas from Lake Maggiore. It is the major component of natural gas, about 87% by volume. The major source of methane is extraction from geological deposits known as natural gas fields, with coal seam gas extraction becoming a major source (see Coal bed methane extraction, a method for extracting methane from a coal deposit, while enhanced coal bed methane recovery is a method of recovering methane from non-mineable coal seams). It is associated with other hydrocarbon fuels, and sometimes accompanied by helium and nitrogen. Methane is produced at shallow levels (low pressure) by anaerobic decay of organic matter and reworked methane from deep under the Earth's surface. In general, the sediments that generate natural gas are buried deeper and at higher temperatures than those that contain oil. Methane is generally transported in bulk by pipeline in its natural gas form, or LNG carriers in its liquefied form; few countries transport it by truck.

Alternative sources

]] Apart from gas fields, an alternative method of obtaining methane is via biogas generated by the fermentation of organic matter including manure, wastewater sludge, municipal solid waste (including landfills), or any other biodegradable feedstock, under anaerobic conditions. Rice fields also generate large amounts of methane during plant growth. Methane hydrates/clathrates (ice-like combinations of methane and water on the sea floor, found in vast quantities) are a potential future source of methane. Cattle belch methane accounts for 16% of the world's annual methane emissions to the atmosphere.Miller, G. Tyler (2007). Sustaining the Earth: An Integrated Approach. U.S.A.: Thomson Advantage Books, , p. 160. One study reported that the livestock sector in general (primarily cattle, chickens, and pigs) produces 37% of all human-induced methane.{{cite book |title=Livestock's Long Shadow–Environmental Issues and Options | url = http://www.fao.org/docrep/010/a0701e/a0701e00.HTM |publisher=Food and Agriculture Organization of the United Nations (FAO) |location=Rome, Italy |year=2006 |author=FAO |accessdate=October 27, 2009}} Early research has found a number of medical treatments and dietary adjustments that help slightly limit the production of methane in ruminants. Research on use of bacteria from the stomach lining of kangaroos (who don't emit methane) to reduce methane in cattle. Alternet.org (January 3, 2008). Retrieved on May 24, 2012. A 2009 study found that at a conservative estimate, at least 51% of global greenhouse gas emissions were attributable to the life cycle and supply chain of livestock products, meaning all meat, dairy, and by-products, and their transportation. More recently, a 2013 study estimated that livestock accounted for 44 percent of human-induced methane and 14.5 percent of human-induced greenhouse gas emissions. Many efforts are underway to reduce livestock methane production and trap the gas to use as energy. Paleoclimatology research published in Current Biology suggests that flatulence from dinosaurs may have warmed the Earth. Dinosaurs passing wind may have caused climate change. Telegraph (May 7, 2012). Retrieved on May 24, 2012.

Atmospheric methane

Methane is created near the Earth's surface, primarily by microorganisms by the process of methanogenesis. It is carried into the stratosphere by rising air in the tropics. Uncontrolled build-up of methane in the atmosphere is naturally checked – although human influence can upset this natural regulation – by methane's reaction with hydroxyl radicals formed from singlet oxygen atoms and with water vapor. It has a net lifetime of about 10 years, and is primarily removed by conversion to carbon dioxide and water. In addition, there is a large (but unknown) amount of methane in methane clathrates in the ocean floors as well as the Earth's crust. In 2010, methane levels in the Arctic were measured at 1850 nmol/mol, a level over twice as high as at any time in the 400,000 years prior to the industrial revolution. Historically, methane concentrations in the world's atmosphere have ranged between 300 and 400 nmol/mol during glacial periods commonly known as ice ages, and between 600 and 700 nmol/mol during the warm interglacial periods. Recent research suggests that the Earth's oceans are a potentially important new source of Arctic methane. Methane is an important greenhouse gas with a global warming potential of 34 compared to CO2 over a 100-year period, and 72 over a 20-year period. IPCC Fifth Assessment Report, Table 8.7, Chap. 8, p. 8–58 (PDF; 8,0 MB) The Earth's atmospheric methane concentration has increased by about 150% since 1750, and it accounts for 20% of the total radiative forcing from all of the long-lived and globally mixed greenhouse gases (these gases don't include water vapor which is by far the largest component of the greenhouse effect).

Clathrates

Methane is essentially insoluble in water, but it can be trapped in ice forming a similar solid. Significant deposits of methane clathrate have been found under sediments on the ocean floors of Earth at large depths. Estimates consider up to 15,000 gigatonnes of carbon may be stored in the form of clathrates (hydrates) in the ocean floor, not accounting for abiotic methane, a relatively newly discovered source of methane, formed below the ocean floor, in the earth crust. It has been suggested, that today's methane emission regime from the ocean floor, is potentially similar to that during the PETM. Arctic methane release from permafrost and methane clathrates is an expected consequence and further cause of global warming.

Anaerobic oxidation of methane

There is a group of bacteria that drive methane oxidation with nitrite as the oxidant, the anaerobic oxidation of methane.

Safety

Methane is nontoxic, yet it is extremely flammable and may form explosive mixtures with air. Methane is violently reactive with oxidizers, halogen, and some halogen-containing compounds. Methane is also an asphyxiant and may displace oxygen in an enclosed space. Asphyxia may result if the oxygen concentration is reduced to below about 16% by displacement, as most people can tolerate a reduction from 21% to 16% without ill effects. The concentration of methane at which asphyxiation risk becomes significant is much higher than the 5–15% concentration in a flammable or explosive mixture. Methane off-gas can penetrate the interiors of buildings near landfills and expose occupants to significant levels of methane. Some buildings have specially engineered recovery systems below their basements to actively capture this gas and vent it away from the building. Methane gas explosions are responsible for many deadly mining disasters. A methane gas explosion was the cause of the Upper Big Branch coal mine disaster in West Virginia on April 5, 2010, killing 29.

Extraterrestrial methane

Methane has been detected or is believed to exist on all planets of the solar system and most of the larger moons. With the possible exception of Mars, it is believed to have come from abiotic processes.
  • Mercury – the tenuous atmosphere contains trace amounts of methane.
  • Venus – the atmosphere contains a large amount of methane from to the surface according to data collected by the Pioneer Venus Large Probe Neutral Mass Spectrometer
  • Moon – traces are outgassed from the surface
(CH4) on Mars – potential sources and sinks.]]
  • Mars – the Martian atmosphere contains 10 nmol/ mol methane. The source of methane on Mars has not been determined. Recent research suggests that methane may come from volcanoes, fault lines, or methanogens, that it may be a byproduct of electrical discharges from dust devils and dust storms, or that it may be the result of UV radiation. In January 2009, NASA scientists announced that they had discovered that the planet often vents methane into the atmosphere in specific areas, leading some to speculate this may be a sign of biological activity below the surface. Mars Vents Methane in What Could Be Sign of Life, Washington Post, January 16, 2009 Studies of a Weather Research and Forecasting model for Mars (MarsWRF) and related Mars general circulation model (MGCM) suggests that methane plume sources may be located within tens of kilometers, which is within the roving capabilities of future Mars rovers. The Curiosity rover, which landed on Mars in August 2012, can distinguish between different isotopologues of methane; but even if the mission determines that microscopic Martian life is the source of the methane, it probably resides far below the surface, beyond the rover's reach. Curiosity's Sample Analysis at Mars (SAM) instrument is capable of tracking the presence of methane over time to determine whether it is constant, variable, seasonal, or random, providing further clues about its source. The first measurements with the Tunable Laser Spectrometer (TLS) indicated that there is less than 5 ppb of methane at the landing site. of Mars by the Curiosity rover.]] The Mars Trace Gas Mission orbiter planned for launch in 2016 would further study Mars' methane and its decomposition products such as formaldehyde and methanol. Alternatively, these compounds may instead be replenished by volcanic or other geological means, such as serpentinization. On July 19, 2013, NASA scientists reported finding "not much methane" (i.e., "an upper limit of 2.7 parts per billion of methane") around the Gale Crater where the Curiosity rover landed in August 2012. On September 19, 2013, from further measurements by Curiosity, NASA scientists reported no detection of atmospheric methane with a value of ppbv corresponding to an upper limit of only 1.3 ppbv (95% confidence limit), and as a result, concluded that the probability of current methanogenic microbial activity on Mars is reduced.{{cite journal |last=Cho|first=Adrian |title=Not a Whiff of Life on Mars|url=http://news.sciencemag.org/space/2013/09/not-whiff-life-mars
| date = September 19, 2013 |work= Science }} On 16 December 2014, NASA reported the Curiosity rover detected a "tenfold spike", likely localized, in the amount of methane in the Martian atmosphere. Sample measurements taken "a dozen times over 20 months" showed increases in late 2013 and early 2014, averaging "7 parts of methane per billion in the atmosphere." Before and after that, readings averaged around one-tenth that level.
  • Saturn – the atmosphere contains 4500 ± 2000 ppm methane
  • * Enceladus – the atmosphere contains 1.7% methane
  • * Iapetus
  • * Titan – the atmosphere contains 1.6% methane and thousands of methane lakes have been detected on the surface.
In the upper atmosphere, methane is converted into more complex molecules including acetylene, a process that also produces molecular hydrogen. There is evidence that acetylene and hydrogen are recycled into methane near the surface. This suggests the presence either of an exotic catalyst, possibly an unknown form of methanogenic life. Space.com. March 23, 2010. Methane showers, probably prompted by changing seasons, have also been observed. On October 24, 2014, methane was found in polar clouds on Titan.
  • Uranus – the atmosphere contains 2.3% methane
  • * Ariel – methane is believed to be a constituent of Ariel's surface ice
  • * Miranda
  • * Oberon – about 20% of Oberon's surface ice is composed of methane-related carbon/nitrogen compounds
  • * Titania – about 20% of Titania's surface ice is composed of methane-related organic compounds
  • * Umbriel – methane is a constituent of Umbriel's surface ice
  • Neptune – the atmosphere contains 1.5 ± 0.5% methane
  • * Triton – Triton has a tenuous nitrogen atmosphere with small amounts of methane near the surface.{{cite journal
| title = Ultraviolet Spectrometer Observations of Neptune and Triton | bibcode = 1989Sci...246.1459B | date = December 15, 1989 | journal = Science | volume = 246 | pages = 1459–1466 | doi = 10.1126/science.246.4936.1459 | pmid = 17756000 | issue = 4936 | last2 = Yelle | first1 = DF | last3 = Linick | last4 = Lunine | last1 = Shemansky | first2 = RV | first3 = J. L. | first4 = J. E. | last5 = Dessler | first5 = A. J. | last6 = Donahue | first6 = T. M. | last7 = Forrester | first7 = W. T. | last8 = Hall | first8 = D. T. | last9 = Herbert | first9 = F. | last10 = Holberg | first10 = J. B. | last11 = Hunter | first11 = D. M. | last12 = Krasnopolsky | first12 = V. A. | last13 = Linick | first13 = S. | last14 = Lunine | first14 = J. I. | last15 = McConnell | first15 = J. C. | last16 = Moos | first16 = H. W. | last17 = Sandel | first17 = B. R. | last18 = Schneider | first18 = N. M. | last19 = Shemansky | first19 = D. E. | last20 = Smith | first20 = G. R. | last21 = Strobel | first21 = D. F. | last22 = Yelle | first22 = R. V. | display-authors = 8 }}{{cite book | title = The Grand Tour: A Traveler's Guide to the Solar System | author = Miller, Ron | authorlink = Ron Miller (artist and author) | author2 = Hartmann, William K. | year = 2005 | pages = 172–73 | publisher = Workman Publishing | location = Thailand | edition = 3rd | isbn = 0-7611-3547-2 }}
  • Plutospectroscopic analysis of Pluto's surface reveals it to contain traces of methane
  • * Charon – methane is believed present on Charon, but it is not completely confirmed
  • Eris – infrared light from the object revealed the presence of methane ice
  • Halley's Comet
  • Comet Hyakutake – terrestrial observations found ethane and methane in the comet
  • Extrasolar planets – methane was detected on extrasolar planet HD 189733b; this is the first detection of an organic compound on a planet outside the solar system. Its origin is unknown, since the planet's high temperature (700 °C) would normally favor the formation of carbon monoxide instead. Research indicates that meteoroids slamming against exoplanet atmospheres could add hydrocarbon gases such as methane, making the exoplanets look as though they are inhabited by life, even if they are not.
  • Interstellar clouds
  • The atmospheres of M-type stars.{{citation
| first1=Uffe G. | last1=Jørgensen | title=Molecules in Astrophysics: Probes and Processes | chapter=Cool Star Models | volume=178 | series=International Astronomical Union Symposia. Molecules in Astrophysics: Probes and Processes | editor-first=Ewine F. | editor-last=van Dishoeck | publisher=Springer Science & Business Media | year=1997 | isbn=079234538X | page=446 | postscript=. | url=https://books.google.com/books?id=VW50otz5v8sC&pg=PA446 }}

See also

Notes

External links

"green air" © 2007 - Ingo Malchow, Webdesign Neustrelitz
This article based upon the http://en.wikipedia.org/wiki/Methane, the free encyclopaedia Wikipedia and is licensed under the GNU Free Documentation License.
Further informations available on the list of authors and history: http://en.wikipedia.org/w/index.php?title=Methane&action=history
presented by: Ingo Malchow, Mirower Bogen 22, 17235 Neustrelitz, Germany